Method of forming pellets of thermoplastic materials



y 1950 1.. w. A. MEYER METHOD OF FORMING PELLETS 0F THERMOPLASTIC MATERIALS Flled Sept 10, 1946 L eszer MA. Mega" IN V EN T Patented May 23, 1950 UNITED STATES PATENT OFFICE METHOD or FORMING PELLETS or THERMOPLASTIC MATERIALS Lester W. A. Meyer, Kingsport, Tenn.,' assignor to Eastman Kodak Company, Rochester, N. Y., a corporation of NewJersey Application September 10, 1946 Serial No. 695,936

12 Claims. 1

;ture of finely divided cellulosic material and plasticizer are rolled on hot rolls to colloidize these components. The rolling action intimately mixes the plasticizer and cellulose base material and exerts a shearing force thereon which tends to {subdivide the hot colloidized material and to produce a homogeneous, uniform composition. At

the end of the rolling treatment, the composition is collected on one roll in a layer. It is then ,manually cut oil the roll and if the composition is .to be employed in injection molding, the layer is broken up and fed to a granulator and thus subdivided into small granules. proximately uniform size are then selected as by .screening, for injection molding uses, the finer or coarser granules being discarded as scrap.

Granules of ap- The granulating operation thus produces.

-. coarse or fine materials which cannot be used to .1, the best advantage in injection molding machines and a selecting operation, which further slows [down and adds to the cost of granule production, .is. required. The necessity of removing fine or .coarse pieces after the granulating operation, as ;,well as the necessity for reworking the coarse and fine scrap stimulated the development of a continuous colloidizing and pelleting process by which only pellets of substantially uniform di- Zmenslon and composition could be rapidly produced.

This continuous process is described and elaimed in U. S. Patent 2,319,040 of May 11, 1943. As stated in that patent, pellets of uniform size and composition are produced by hot rolling finely divided particles of the organic base material of the plastic composition with plasticizer and, ii desired, with fillers and/or coloring materials. on a pair of parallel positioned rolls, one of which at least is maintained at a temperature above that of the boiling point of water, and more partlcularly within a range of from 212 F. to 370 F.

Preferably, the temperature of one roll is main- 2 tained higherthan the By continuously adding a uniform amount of the mixture at one end of these relatively closely spaced rolls, which rotate in opposite directions, the resulting thermoplastic mass will work gradually around and along the rolls, during which it will become thoroughly colloidized and collect on the hotter roll from which a narrow relatively thin strip of the colloidized plastic mass can be continuously removed adjacent the end of the roll remote from the feed end. This narrow. thin strip is positively cooled somewhat and is sliced lengthwise and is then cross cut while still in a heat softened state. into very short uniform lengths thereby producing pellets of the plastic composition of substantially uniform dimensions. Because the strip is relatively soft and pliable while being cut. substantially all of the composition is made into pellets which are well adapted for use in injection molding processes. The hot cutting eliminates fines normally produced when cold cclloidized plastic materials are granulated by methods formerly employed in this industry and the predetermined setting of the slicing and cross cutting devices regulates the size of the pellets.

This process has been very successful in con-- tinuously producing thermoplastic pellets from a great variety of compositions. Recently, however, there have been developed several new plastic compositions which give considerable difficulty when colloidized by the above described continuous pelleting process. This difficulty arises from the fact that when the rolls are operated hot enough to secure the required colloidization. these particular plastic compositions adhere to the rolls and cannot be continuously stripped therefrom. It. therefore. appeared that the most practical manner of making pellets from these newer compositions was to employ the former batch process and strip the composition from the rolls by hand in accordance with the old more expensive practice.

An object, therefore. of the present invention is a continuous process for the production of pellets of uniform size from organic thermoplastic materials which are very tacky at temperatures required for colloidizing those plastic materials.

Another object of the invention is an improve-'- ment of the process described in U. S. Patent 2,319,040 whereby plastic compositions, which are extremely tacky at temperatures required for colloidizing the composition, may be continuouslyother so that the composition will gradually collect on the hotter rolL.

3 colloidized and continuously removed in a strip from the milling rolls without difficulty.

' .Still another object is a colloidizing process by Which the temperature of the colloidizing operation may be more suitably regulated to the requirements. of the plastic being colloidlzed.

In accordance with one, feature of the present.

invention, these and other objects are attained by employing the general process of Patent 2,319,040, but employing the added step of dilifem...

entially controlling the temperature.along .the

length of, at least, the front roll"fromwhich therr strip of colloidized plastic is removed. Adjacent 1 the place at which the uncollo.idiz ed.;material;isafiadded to the rolls, the front rolltemperatureaiszz cooler to permit the continuous removal of a strip, of colloidiged material. The temperature of the-coasting back roll could be similarly regulated having high temperature sections at its 1 ends and alower'temperature section at its middle maintained high to permit colloidization of theplastic mixture. As the collqidized material. pro:

gresses around and along the front roll toward the end at which the colloidized homogeneouslymixed plastic composition is taken off in a strip, L

theitemperature, of the; roll; islowdliedwp Ears-$9; coolztheiplastic below-the temperature at; which itowillitendto. disadvantageously adhere torthe front. or, back' rolls. Thus when, it reaches the;

' point. Where it, is continuously removedrthe plas tie strip; although still quite hot;wil1 continuously7 leave-the front rollsinqa substantially.nonesticlge.

ing form; Inthesimplest form of operation; the.

loi iaed plasti -:...mix w is ;added. may. be maintained,

ab .etlle 1 zine t mseratu e.of th a ti mixand sect ons adiacerittheends.wher he. iscont mlQuSlY removed maybe maintained lwtthe em s tur atr iqh h di b Plasti M L-r sist. b in emqve i. r the rolls ini a continuous strip. For colloidizing isom e' compositions it maybe desirable to maintain each roll section at different temperatures. In general operation, the roll from which the strip is re moved will be somewhat hotter than the other r011.

- In accordance with still another feature of the invention; the thermoplastic mixture may be centinuously added at approximately the mid section of the coa'oting rolls' and-permitted to? work betw een therolls and around. the front hdfitrroll toward the opposite ends of-th'e-front roll, a strip of the colloidized' plastic being re moved iro'm each'end ofthe front-irons: Under; such operating conditions, the center section-goiat least the front roll would be.:heated-:to or above the colloidizing temperature of-"the. plastic mix being colloidized and the 'opposite end sections oi the front rollwould be maintainedorelatively.

coolerto permit theremoval-o-the pair of.-col.- v

. should be-relatively; lower than: the;correspcmd v ingesections of: the-front roll so. thatthe composi-r.

" than: being ;r,o1led will: tend to accumulate ornthe hotter .front roll.

= In: accordance; with another.featureot-the invention, the thermoplastic. mixturemay beadded s i multaneously at .theoppgsite end sections oi the;

processofthelinventiont; a

. portion- Againit is=emphasized that the temperatures of the back roll shoud be relatively lower than the corresponding sections of the front rollt'o'assure that the composition will accumulate on-:the..front roll to facilitate its removal in a strip. 7

' h le-Jim des ab e-1 man ns an s employ a backroll having; provision for separately. sesame h m e e along s len th, in somecasesa satisfactory operation is attained by.

employing aback roll ;;main;tainedate a substantially-uniform temperature.- Thus,-a back;ro 1l: having a single temperature control may beeerngef ployed oronemay beemployedhavinga plurality; of temperature controlled sections;whicrrin the; particular operationv aremaintainedsat the-. same tempenatura.

The-Y temperature.v of the. rolls may. be -main tained; by employing any, suitable.- heating and. cooling devicesl p ffiferftoaemploy. hollow-rolls; each having a, plurality. of. separate. unconnected. compar'trnelnts,into geach of which heating and. cooling. fluids maybe. introduced-as requiredby. the. conditions, of operation Generally; thm colloidizingtemperature will be above. 212?. Bland in a range, of. 2 12? to, 370- .Preierablythe. roll from.whichtheplastic is removedin a strip. is maintained .from 202 F .,to. 100 F or. more higher than the temperature or theother roll. so thatthe, composition. will". gradually collect. there By continuously; adding. a. uniform amount of--. the mixture. atsone end, of the pair of .relatively closely spacedj rolls" which. rotate .in opposite. di-f rectionsthe.resulting. thermoplastic mass. will work gradually aroundand. along the rol ls,.during'. whiehit will become. thoroughly colloidized' by contact. with." the. higher.- heated sections of the, rolls and, subsequently. cooled, belowv its. tacky pointgbygcontact. with thacooler. seo.. tionsoithe rolls... A.narr0.w relatively thin strip.

" o fithepolloidized plasticmass canbe continuously;

remoyedjrom the cooled, end section of. the front roll. If desired, .thisnarrow. strip. may. beLfur ther. cooledsomewhat. after; it-1ea.ves the; rolls, but itis cut lengthwise and thencrosswisewhile; it. is stilljin a softstateintovery.shortlengths. thereby pro.du.cing pellets of. substantially form dimensions. Because the strip is relatively. softwhilebeing cut, substantially allpf. the..cic' 'niposition is; made: into. usable pellets; without any.fines.f. V

. The invention .will. be. further .understood hy. reference to. the. following. detailed. description; and,drawi ngsin which:

Fig 1 is. a diagrammaticplan view.of -the.pre-,. ferred, apparatus. for:.use. ..ii1.carrying, out the.

.Fig. 2 is a diagrammatic elevationalview of the, apparatus showrrin.Fig. il.;,and 1 r 75 Fig.3 is aview vof the pairsof double .eham e-r atoms bered rolls showing the fluid inlet and outlet system by which the temperature in any one chamber can be maintained the same or different than the temperature in the other chambers.

The present invention is described with particular reference to cellulose acetate butyrate plastics, but the process is equally applicable to the continuous production of improved 'plastic products from any of the various cellulose organic derivatives, such as cellulose acetate, cellulose propionate, cellulose butyrate, cellulose acetate propionate, methyl cellulose, ethyl cellulose, benzyl cellulose, as well as the thermoplastic resins such as acetal resins and others known to the art. I

The initial step in preparing molding compositions from these derivatives is the mixin g of an appropriate amount of the finely divided base material of the composition with a compatible plasticizer and any other material suchxas dyes, pigments, pearl essence or other nacreous materials, fillers and the like which may be desired. While various types of mixers may beemployed,

one may use the type of mixer and, if applicable,

the method described in U. S. Patent 2,150,939 of March 21, 1939.

Referring to Figs. 1 and 2 of the instant application, there is shown apparatus comprising a hopper I0, adapted to contain an uncolloidized plastic mixture I3, positioned above a pair of rolls I I and I2 which are adapted to rotate in opposite directions. If desired, a plate or other suitable mechanical device not shown can be associated with the ends of the rolls adjacent the hopper to retain the mixture on the rolls. Roll II has two hollow chambers 6 and 1 therein and roll I2 has two hollow chambers 8 and 9 therein which are associated as shown more'clearly in Fig. 3 with fluid inlet conduits 5 and fluid outlet "conduits 4 which are respectively connected to a source of fluid and a return as will be understood. Steam, hot and cold water may be advantageously employed to provide the desired temperatures in all or any of the chambers. In accordance with an important feature of this invention, the effective surface temperatures of the rolls along their length can :be' differentially regulated'by introducing fluids at different temperatures into the respective chambers. The end sections of the rolls beneath" the hopper which come into first contact with the uncolloidized plastic mixture continuously flowing from the hopper I may be maintained at approximately the colloidizing temperature of the mixture by introducing hot fluids into chambers i and 8 and the opposite end sectionsof the-rolls may be maintained relatively cooler by introducing cooler fluids into chambers I and 9 so as to reduce or eliminate the tackiness of the colloi dized plastic I4 and permit it to be continuously removed in a strip I8 by stripper knife I which is mounted on support It and held against roll II by spring II.

A pair of air jets 2! and 22 are positioned near the roll II for cooling the strip l8, and draw off rolls23 and 24 pull the strip I8 from the roll II and between air jets 2| and 22. Longitudinal slicing rolls 2! and ZB'draw' the strip I8 through a second set of cooling air jets 25 and 26 and slice the strip I8 into a plurality of narrow strips 33. These rolls are so positioned that thecutting members of the respective rolls will slightly enter and rotate in the grooves of the Opposite roll, leaving, however, a space for the slit material to pass. These strips 33 are then conducted 6'- across platen 29 to engage the rotary cutter 30 which operates continuously to cut the soft narrow strips into uniform lengths thereby forming pellets 3| of predetermined dimensions which are collected in bin 32.

If desired, bin 32 may be suitably cooled, by means not shown, to bring the temperature of the pellets quickly down to room temperature. If the pellets of some materials tend to adhere into clusters in the bin, they may be caused to slide over a cooled chute to lower their temperature before they pile up in the bin.

drawings are mounted to rotate and may be caused to rotate by suitable mechanisms not shown. If desired, rolls II and I2 may both be driven at the same or difierent rates. If differentially driven, the front roll II would generally be driven at the faster speed. The rolls II and I2 are also mounted on means not shown so that the space between the rolls can be adjusted to suit any particular conditions of operation. By suitable adjustment of this space, the thickness of the pellet can be determined. In general, the pellet size is from A to 1% inch square, although as above suggested pellets having other rectangular shapes may be produced by suitable adjustment of the rolls and the slicing and cutting.

devices.

Example I partscellulose acetate butyrate mixed with l5parts methoxyethyl stearate are added to the hopper I0 and permitted to flow continuously onto the revolving rolls II and I2 at one end where it is worked therebetween. The temperature of the front roll II above chamber 6 was approximately 240 F. and above chamber 1 was approximately 215 F. The temperature of the back roll I2 above chamber 8 was approximately 220 F. and above chamber 9 was approximately F. The front roll II being of a relatively higher temperature will pick up the plastic layer I4 a short distance away from the feed end of the rolls and it will work spirally around the rollto its opposite end. The thermoplastic composition owing tothe heat and mixing action of the rolls becomes colloidized and homogeneouslyv mixed. However, because the temperature of the section of the roll above chamber 1 is below the temperature at which the thermoplastic is extremely tacky, a narrow strip I8 can be continuously cut off the layer I4 by knife I5 and continuously conducted through the subsequent parts of the apparatus as heretofore explained. The amount of material leaving the rolls in strip I 8 is equivalent to the amount of new material being continuously added on the input end of the rolls.

Example II Pellets were continuously made in accordance with the above described process from a composition containing:

Parts Cellulose acetate butyrate 100 Dibutyl sebacate 13 Phenyl salicylate 1 atu e the ppo i e s ction. 01- the front r011 W384 hale-$23021 and the back roll t 23o 1:5 w t ut-em l yin the o le. wmea tment l s n such temp rature. control, it is imnoss bl t pmduce continuously pellets fromthis-material on,

this y appara u V K93117 411CfI I; Av mixture containing z Cellnlosezacetatobutyrate 4,- Methoxyethyl stearate was continuously added to the pelleting apparatu as "described above. The heating sectionoff the 'front roll adjacent the h op'pner was held at 359' F. to colloidize the mixture and the corresponding section of the back'roll was held at 300 F. The cooling section of the front roll was held' at 32Q"F. and that-bf the back roll at 230 FL Uniiorm sized, pellets were produced under these conditions at a rapid irate without difllculty due to adhesion of the plastic to the roll;

Example IV Amixture containin Parts qllulo'seacetate butymtenssnew??? lDQ. Butyl stearateV.-, H s 13.3 Butyi 'sebacate 2 0 were processed in theipelleting apparatus. The

roll temperatures mostsuitab-le for this plastic composition are; front roll colloidizingsection 195 F corresponding section on back roll 23TH; cooling section oi front 215' F. and of back roll 1 145 F1 Pe lets of uniform size and of homogenous composition were continuously formed under these conditions. 7

Th above examples describe typical adjustmentsofrollsection temperatures for the production of pellets fronitherpnoplastic compositions which cannot be rolled and cutinto pellets Without such temperaturecontrol. It has been found that in general the take ofi enclof the front roll'should be from '20 to 25' degrees cooler than {1;

the hopper end. 'lhebaclgrollshould also have about the same temperature differential as the v front roll-and also should be at least 20 to 30' t legi'ees cooler than the corresponding points 1 of the-front roll. 7

Example V A,.Qontinuou s. strip. was, made incraccordallfiec with: the inMentiDn from a csmposi ion containing; s I

p 4 p Y Pa ts Cellulose acctate butt/rates 1.

D butyl Dhthalate. floss, The temperature of the 'sectionofthe front roll beneath the feed' hopper was maintainedz at 290 F. and the corresponding: section of the back roll was maintained at 270 To prevent this compound from disaclvantageously"adhering to the rolls adjacent to the stripping knife,- the tern peratnre of the opposite section "of the front roll washeld at 280 F. and the back roll at 2305B. As the strip left the front roll; it was passed throng-tithe cooHng'dev-ices -24 and 22 shown in Figs.- 1 and 2 of the drawing and was further eoledbr being wound in a spiral path ar und a lwge \turningflcold. r011, not shown, from whence it, was'ici ct dto a wind. up toll, not shown,- and, wound into a roll. The material in strip form may be emp oye o various pu poses. mma be out, intojlareie sections and mployes s'incomr phasis hasbeen made herein particularly top d ins sal tsi r use in inje io m d n op 3 ablewior" use to -iOlfm. strips, and pellets 'fro a h-1:011, it; is entirel in thepurviewofi th in 8: nrsssion: mo ding. sera lens QPQW- s ip m y elendete land rimm d cot-us in mak nswnve s chair-sea amt. e. li e In some instancss it' may e des r b e tote:

a: move ultipl strips from the roll by employin c b s inn. s. Batentfi26 693 o er is. 1 31 While thisprocess is particularly adaptable for the'proquction of-cc-ntinuous strips orpellets oi: p ast eco no itiens wh ch ar ma at ello; ns tsmerat res.- ta 0 s adaptable and di -s t other compositions which are not part; a-r askyat h r o cie m t p a ure fact, a substantial reductionlin process tfnne has e n n e w e com itic lssu h as t seds s clo e n Exam les e l-oi et zfila q made intopel e s-by he-i stant proc ss pnea s duen part. o, t e better t m erat 7 control obtained by employinghcollo-igiizing r is hai n p u a ro -temp r tu sulstln mea-ns Itv is, hs e c my t nt to s v th s v xamp e by reier nes thisv ep lie'et. as: ypical ofth composit ns h ch ane ad ae us y pr cessed n cco d n w h the instantim/ ntibn 'I 'o ill -gstrate-thisprocess, Figs. 1 and 2 of the drawing ha e bee m so ewhat s m e t Figs. 1 angLZ .ofPatent 2,319,040. It will be ders ood, h weve he s n ven n equal y aqap able or use with the p mtus: V

s q iniss-"i and 5. o ha p tent. pro-- vices thecqlleidi i g r ls are equippeq with tip ech xmbers a h einde c lbe Fur he mere.= hi;le t e inve en is tra ts i witch'rollsl havi g n y two s a a le s amberc ventign to have more th temp a echamb or o h r-tempe atu e n o lin eans: ineach roll to regulate the surface temperaturei the rolls along their length.

It will also e understo. d t t o gh ems;

tions that depending on their compositionthe yi be employ d, tomnanyoth r uses, nd theres: no intent o imit the following claims-re 7 s eets t use th produc ,I, claim;

1. The continuous process of i'orngingstrips-ofi olloid zed organic. thermo as c o p' iti n which comprises continuouslyatlgiing a .GOHQidiZm. abl -m xtu e not an or a c h rmo las i am pcund'an a plasti i e c a ai o a llel. close -spa edfml r 0 c nu 0.15 eidi iae he m xtu e-t f rm a on-iogenequs thermoplastic, composition by working it between opposing iarallei sections of the respective rolls, one ofwhichjsect ioj heated to at least the;

collo d i g t npenetur of the m xt r wh y, e lco oisi zed mix u em yes piroeiressiye y a q e and. a en the ol htvinspt e e e ec onin the form of a continuous coherent blanket, continuously cooling the colloidized thermoplastic blanket between other cooler opposing sections of the rolls to a temperature at which it is more easily stripped from the'roll, and continuously removing a strip of the progressively moving coherent colloidized composition from said roll at a point remote from the point at which the material is added and colloidized but at or adjacent said cooled section of the roll to which the composition has adhered, the rate of addition of the material and its removal in the strip being substantially equal.

2. The continuous process of forming colloidized organic thermoplastic compositions into desired shapes, which. comprises continuously adding a colloidizable mixture of an organic .thrmopl'astic compound anda plasticizer to a pair of parallel closely spaced milling rolls, continuously colloidizing the mixture to form a homogeneous thermoplastic composition by working it between opposing parallel sections of the respective rolls, one of which sections is heated to at least the colloidizing temperature of the mixture whereby the colloidized mixture moves progressively along and around the roll having the hotter section in the form of a continuous coherent blanket, continuously cooling the colloidized thermoplastic blanket between other cooler opposing sections of the rolls to a temperature at which it is more easily stripped from the roll, continuously removing a strip of the progressively moving coherent colloidized composition from said roll at a point remote from the point at which the material is added and colloidized but at or adjacent said cooled section of the roll to which the composition has adhered, the rate of addition of the material and its removal in the strip being substantially equal, at least partially cooling the strip and cutting the strip into relatively short lengths, pellets and the like.

3. The continuous process of forming strips of colloidized cellulose organic ester thermoplastic compositions, which comprises continuously adding a colloidizable mixture of the cellulose ester and plasticizer to a pair of parallel closely spaced milling rolls, continuously colloidizing the mixture to form a homogeneous thermoplastic composition by working it between opposing parallel sections of the respective rolls, one of which sections is heated to at least the colloidizing temperature of the mixture whereby the colloidized mixture moves progressively along and around the roll having the hotter section in the form of a continuous coherent blanket, continuously cooling the colloidized thermoplastic blanket between other cooler opposing sections of the rolls to a temperature at which it is more easily stripped from the roll, and continuously removing a strip of the progressively moving coherent colloidized composition from said roll at a point remote from the point at which the material is added and colloidized but at or adjacent said cooled section of the roll to which the composition has adhered, the rate of addition of the material and its removal in the strip being substantially equal.

4. The continuous process of forming colloidized cellulose organic ester thermoplastic compositions into desired shapes which comprises continuously adding a colloidizable mixture of the cellulose ester and plasticizer to a pair of parallel closely spaced milling rolls, continuously colloidizing the mixture to form a homogeneous thermoplastic composition by working it between opposing parallel sections of the respective rolls, one of which sections is heated to at least the colloidizing temperature of the mixture whereby the colloidized mixture moves progressively along and around the roll having the hotter section in the form of a continuous coherent blanket, continuously cooling the colloidized thermoplastic blanket between other cooler opposing sections of the rolls to a temperature at whichit is more easily strippedfrom the roll, continuously removing a strip of theprogressively moving coherent colloidized composition from said what a point remote'from the point at which the material is added and colloidized but at or adjacent said cooled section of the roll to which thecomposition has adhered; the rate of addition of the material and-its'removalinthe strip being substantially equal at least partially cooling the strip and cutting the strip into relatively short lengths, pellets and the like.

5. The process of claim 3 in which the cellulose organic ester is cellulose acetate.

6. The process of claim 3 in which the cellulose organic ester is cellulose propionate.

7. The process of claim 3 in which the cellulose organic ester is cellulose acetate butyrate.

8. The process of claim 4 in which the cellulose organic ester is cellulose acetate.

9. The process of claim 4 in which the cellulose organic ester is cellulose propionate.

10. The process of claim 4 in which the cellulose organic ester is cellulose acetate butyrate.

11. The continuous process of forming strips of colloidized organic thermoplastic compositions, which comprises continuously adding a colloidizable mixture of an organic thermoplastic compound and a plasticizer to a pair of parallel closely spaced milling rolls having a plurality of temperature controlled sections therein, continuously colloidizing the mixture to form a homogeneous thermoplastic composition by working it between two opposing parallel sections of the respective rolls, one of which sections is heated higher than the other and to at least the colloidizing temperature of the mixture whereby the colloidized mixture moves progressively along and around the roll having the hotter section in th form of a continuous coherent blanket, continuously cooling the colloidized thermoplastic blanket between two other cooler opposing sections of the rolls, one of which is heated higher than the other, to a temperature at which it is more easily stripped from the roll, said higher heated sections being in the same roll, and continuously removing a strip of the progressively moving coherent colloidized composition from said roll at a point remote from the point. at which the material is added and colloidized but at or adjacent said cooled section of the roll to which the composition has adhered, the rate of addition of the material and its removal in the strip being substantially equal.

12. The continuous process of forming colloidized organic thermoplastic compositions into desired shapes, which comprises continuously adding a colloidizable mixture of an organic thermoplastic compound and a plasticizer to a pair of parallel closely spaced milling rolls having a plurality of temperature controlled sections therein, continuously colloidizing the mixture to form a homogeneous thermoplastic composition by working it between opposing parallel sections of the respective rolls, one of which sec- 

1. THE CONTINUOUS PROCESS OF FORMING STRIPS OF COLLOIDIZED ORGANIC THERMOPLASTIC COMPOSITIONS, WHICH COMPRISES CONTINUOUSLY ADDING A COLLOIDIZABLE MIXTURE OF AN ORGANIC THERMOPLASTIC COMPOUND AND A PLASTICIZER TO A PAIR OF PARALLEL CLOSELY SPACED MILLING ROLLS, CONTINUOUSLY COLLOIDIZING THE MIXTURE TO FORM A HOMOGENEOUS THERMOPLASTIC COMPOSITION BY WORKING IT BETWEEN OPPOSING PARALLEL SECTIONS OF THE RESPECTIVE ROLLS, ONE OF WHICH SECTIONS IS HEATED TO AT LEAST THE COLLOIDIZING TEMPERATURE OF THE MIXTURE WHEREBY THE COLLOIDIZED MIXTURE MOVES PROGRESSIVELY ALONG AND AROUND THE ROLL HAVING THE HOTTER SECTION IN THE FORM OF A CONTINUOUS COHERENT BLANKET, CONTINUOUSLY COOLING THE COLLOIDIZED THERMOPLASTIC BLANKET BETWEEN OTHER COOLER OPPOSING SECTIONS OF THE ROLLS TO A TEMPERATURE AT WHICH IT IS MORE EASILY STRIPPED FROM THE ROLL, AND CONTINUOUSLY REMOVING A STRIP OF THE PROGRESSIVELY MOVING COHERENT COLLOIDIZED COMPOSITION FROM SAID ROLL AT A POINT REMOTE FROM THE POINT AT WHICH THE MATERIAL IS ADDED AND COLLOIDIZED BUT AT OR ADJACENT SAID COOLED SECTION OF THE ROLL TO WHICH THE COMPOSITION HAS ADHERED, THE RATE OF ADDITION OF THE MATERIAL AND ITS REMOVAL IN THE STRIP BEING SUBSTANTIALLY EQUAL. 